金属有机框架衍生单原子纳米酶的合成、表征与生物应用研究进展

单原子催化剂（SACs）具有高原子利用效率以及高催化活性，在各种催化体系中均表现出优异的性能.其原子级别的活性位点与天然的金属蛋白酶类似，因此单原子纳米酶（SAzymes）的概念也应运而生.而金属有机框架（MOF）由于其具有高孔隙率的特点，可以作为合成SAzymes的前驱体.该文总结了使用MOF前体/模板构建SACs的合成策略，以及SAzymes的生物应用，提出了基于MOF衍生的SAzymes的发展挑战和前景.     

外场与腔场非共振驱动Jaynes－Cummings系统的准能解

本文主要求出了Ｊ－Ｃ系统受与腔场非共振的外场驱动时的准能级及态的近似表达式，设外场与腔模的失谐量△_ｃ远小于耦合常数ｇ，并且腔模光子数较小，在计算中可略去。结果可知，失谐量△_ｃ存在使能级中心位置移动，但对能级分裂量没有影响。相应的光场态为两个位移福克态的叠加。     

Titius—Bode定则的发展,天体量子论和泛量子理论

太阳系的Titius-Bode定则可以发展为r_n=an~2,令α_1=0.042,n=3,4,5,6是类地行星;令α_2=1.2,n=2,3,4,5,6是类木行星。此时海王星、冥王星都是规则的,且适用于大多数卫星。由此可以完全类比于玻尔原子模型,并得出太阳系量子常数H=(αGM_⊙)~(1/2)和天体薛定谔方程。这样距离规则是行星演化时统计性的结果,宇宙中应普遍存在波粒二象性和形式相似而量子常数各不相同的泛量子理论。     

苦丁茶与常用茶中微量元素分析

苦丁茶又称苦丁、苦簦、皋卢等 ,是我国南方和东南亚地区常饮的代用茶 .几千年民间饮用和现代医学验证苦丁茶具有清热解毒、杀菌消炎、活血脉、降血脂、降胆固醇等功效 .近 10年来 ,科技人员对苦丁茶的化学成分进行了多方面的研究 ,确定其中含有化学成分达 2 0 0多种[1] ,一部分与普通茶叶相同 ,如咖啡碱、多酚类、儿茶素、氨基酸等 ,但含量比普通茶叶低[2 ] ,此外 ,苦丁茶还含有熊果酸 (Ｕｒｓｏｌｉｃ ａｃｉｄ)、β 香树脂醇 (β Ａｍｙｒｉｎ)、蛇麻脂醇 (Ｌｕｐｅｏｌ)、熊果醇 (Ｕｖａｏｌ)和 β 谷甾醇 (β Ｓｉｓｔｅｒｏｌ)等 .但…     

高Q-腔中量子化平移运动与原子内态布居的关系

讨论了在驻波腔场中两能级原子的量子化平移运动与原子内态布居间的相互影响。结果表明原子量子化平移运动敏感地依赖于原子的内态布居。     

用玻尔理论测量普朗克常数

提出用玻尔氢原子理论测量普朗克常数的原理和测量结果。     

Improvement in hydrogen storage performance of Mg by mechanical grinding with molten salt etching Ti3C2Clx

Mg-based materials are currently a hot research topic as hydrogen storage materials due to their considerable theoretical hydrogen storage capacity. However, the kinetic performance of hydrogen absorption and desorption of Mg is too slow and requires high temperature, which seriously hinders the application of this material. MXene is a new type of two-dimensional material with significant role in improving thermodynamics and kinetics. In this experiment, a two-dimensional layered MXene containing Cl functional group was prepared by molten salt etching using the Ti-containing MAX phase as the raw material. Then different ratios of Ti₃C₂Cl_x were uniformly dispersed onto the surface of Mg by high energy ball milling. The samples were characterized by hydrogen absorption and desorption kinetics, SEM, XRD, XPS, and DSC to investigate the effect of Ti₃C₂Cl_x on the hydrogen absorption and desorption performance of Mg. The onset hydrogen absorption temperature can be reduced to room temperature and the hydrogen release temperature is reduced by 200 ​°C by doping Ti₃C₂Cl_x. And there is also 5.4 ​wt% hydrogen storage in the isothermal hydrogen absorption test at 400 ​°C. The results of DSC demonstrate that the E_a of Mg+15 ​wt% Ti₃C₂Cl_x was reduced by 12.6% compared to pristine Mg. The ΔH is almost invariable. The results of XPS show that the presence of multivalent Ti promotes electron transfer and thus improves the conversion between Mg²⁺/Mg and H⁻/H. This study provides a guideline for further improving the hydrogen absorption and desorption performance of Mg-based hydrogen storage materials.     

贮氢合金的开发与研究进展

贮氢合金是近年来开发的一类新型高性能材料。本文介绍了贮氢合金的开发和研究的最新进展,论述了它在氢的提纯、热泵、空调、压缩机和镍—氢化物电池等高技术领域中的应用前景。     

非谐振多光子过程的原子压缩效应

考虑非谐振情况下的多光子跃迁过程,在ｋ≥ｒ⊥,ｒ∥的条件下,利用绝热近似方法,由线性Ｆｏｋｋｅｒ－Ｐｌａｎｃｋ方程导出此过程的原子压缩表示式。     

Ru原子高Rydberg态能级的唯象势计算

将文[4]提出的用于碱金属原子的唯象势推广到一般原子的高Rydberg态,并对Ru原子4d7（4F）ns（n＝28－45）和4d7（4F）nd（＝26－48）系列的Ryd－berg能级进行PWKB计算．在理论值与实验数据之间进行比较的基础上,讨论了所得结果的物理意义．